By John Comyn
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Extra resources for Adhesion Science
The product contains 1% of S and 25-43% of C1 by weight. ATBN and CTBN are acronyms for copolymers of butadiene and acrylonitrile with either amine or carboxylic end groups. About 85% of the butadiene units are in the trans-174-configuration and molar masses are typically 3500. In an epoxide adhesive the end groups will react with the resin so there will be chemical bonding at the particle-matrix interface. 2Nm-' on adding 20% by weight of CTBN. SILICONES One-part silicone adhesives are often termed room temperature vulcanizing (RTV), and consist of poly(dimethy1 si1oxane)s(PDMS) with molar masses in the range 300-1600, with acetate, ketoxime or ether end groups.
B) Immerse for 5 rnin at 40 "C in trisodium phosphate 25 g, Teepol detergent 5ml and water to make 11. (c) Anodize in phosphoric acid 60ml and water to make 11 at room temperature. Raise voltage to 1OV over 2min. and maintain for 5 min. (d) Spray rinse with cold water. (e) Dry in an air-circulating oven at no greater than 45 "C. A chromic acid anodizing procedure recommended by Ciba Composites is: (a) As for chromic acid etching. (b) Anodize in chromium trioxide 500g and water to 101 at 40°C. Raise to 40 V over 10 rnin and maintain for 20 min.
Tetramethylolurea has not been isolated. 5 All these compounds undergo condensation polymerization uia methylol groups, to give crosslinked products. The reactions take place at ambient temperatures after the addition of a catalyst. The adhesives are water-based and water is produced on curing; it is removed by migration into the wood, making these adhesives only suitable for porous adherends. ACRYLIC ADHESIVES Structural adhesives containing acrylic monomers are cured by freeradical addition polymerization at ambient temperatures.
Adhesion Science by John Comyn