By Marco Bandini

ISBN-10: 3319351427

ISBN-13: 9783319351421

ISBN-10: 3319351443

ISBN-13: 9783319351445

The sequence themes in Heterocyclic Chemistry provides serious experiences on current and destiny tendencies within the learn of heterocyclic compounds. total the scope is to hide themes facing all parts inside of heterocyclic chemistry, either experimental and theoretical, of curiosity to the final heterocyclic chemistry neighborhood. The sequence contains subject similar volumes edited by means of popular editors with contributions of specialists within the box. All chapters from issues in Heterocyclic Chemistry are released on-line First with somebody DOI. In references, themes in Heterocyclic Chemistry is abbreviated as best Heterocycl Chem and brought up as a journal

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Volz F, Wadman SH, Hoffmann-Roder A, Krause N (2009) Gold catalysis in stereoselective natural product synthesis: (+)-linalool oxide, (-)- isocyclocapitelline, and (-)-isochrysotricine. Tetrahedron 65:1902–1910 41. Gao ZH, Li YF, Cooksey JP, Snaddon TN, Schunk S, Viseux EME, McAteer SM, Kocienski PJ (2009) A synthesis of an ionomycin calcium complex. Angew Chem Int Ed 48:5022–5025 42. Sawama Y, Sawama Y, Krause N (2008) First total synthesis of (R, R, R)- and (3R,5S,9R)bejarol by gold-catalyzed allene cycloisomerization and determination of absolute configuration of the natural product.

Alternatively, Echavarren and coworkers reported a gold(I)-catalyzed cycloisomerization of 1,6-enynes 178, bearing an O-allyl group at its propargylic position. The reaction is proposed to involve an intramolecular 1,5-migration of the O-allyl group (179) affording an α,β-unsaturated gold–carbene/allyl gold cation 180. This species undergoes an intramolecular cyclopropanation to yield the final tricyclic compound 181 (Scheme 61) [167]. L. Mascare~ nas and F. 3 Oxycyclizations Followed by Rearrangements Liang and coworkers reported in 2008 a gold-catalyzed tandem cyclization/[1,2]alkyl migration of epoxyalkynes like 182 to afford spiropyranones of type 184 with good yields and in an stereospecific manner [168].

Trost BM, Dong GB (2008) Total synthesis of bryostatin 16 using atom-economical and chemoselective approaches. Nature 456:485–488 54. Ru¨ttinger R, Leutzow J, Wilsdorf M, Wilckens K, Czekelius C (2011) Reversal of selectivity in gold-catalyzed cyclizations of 3,3-disubstituted 1,4-diynes. Org Lett 13:224–227 55. Wilckens K, Uhlemann M, Czekelius C (2009) Gold-catalyzed endo-cyclizations of 1,4-diynes to seven-membered ring heterocycles. Chem Eur J 15:13323–13326 56. Murai M, Uenishi J, Uemura M (2010) Gold(I)-catalyzed asymmetric synthesis of planar chiral arene chromium complexes.

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Au-Catalyzed Synthesis and Functionalization of Heterocycles by Marco Bandini

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